化工社化工社 化学情報印刷レポート · 研究参考用
Sodium Acetate → Methyl dihydrojasmonate, cis-(+)-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Sodium Acetate | HCID 517045 | — |
| 反応物 | methyl (+)-(1R,2S,3R)-3-hydroxy-2-pentyl-1-cyclopentaneacetate | HCID 7075801 | — |
| 反応物 | HCID 178418287 | HCID 178418287 | — |
| 生成物 | Methyl dihydrojasmonate, cis-(+)- | HCID 1738122 | 94.9% |
反応手順
This ester (2.85 g) was then oxidized by means of PCC, in the presence of sodium acetate, in a manner analogous to the method described in Example 1 d), to yield 2.68 g of the desired methyl (+)-(1R)-cis-3-oxo-2-pentyl-1-cyclopentaneacetate (colorless oil; purity 98.5%; yield 92.7%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05728866 |
| 出典データセット | uspto-grants-1998_03 |
| ORD ID | ord-5e5ea1bad7f34a958fa0ed6555062f7d |
| 出典メモ | uspto-grants-1998_03 |