化工社化工社 化学情報印刷レポート · 研究参考用
3-Methyl-2-cyclohexen-1-one → 3-Methyl-2-cyclohexen-1-one
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 3-Methyl-2-cyclohexen-1-one | HCID 14511 | — |
| 反応物 | HCID 178418373 | HCID 178418373 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | 3-Methyl-2-cyclohexen-1-one | HCID 14511 | — |
| 生成物 | Cyclohexanone, 3,3-dimethyl- | HCID 76322 | — |
反応手順
First, 3-methyl-cyclohexenone was prepared in accordance with the procedures of Jirgensons et. al., Euro. J. Med. Chem. 35 (2000) 555-565. Then, 3-methyl-cyclohexenone was reacted with methyl magnesium iodide in the presence of cuprous chloride in diethyl ether to obtain the title compound.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08642603B2 |
| 出典データセット | uspto-grants-2014_02 |
| ORD ID | ord-f2ed5d56b2764e25bcbeb6e69c3a3e53 |
| 出典メモ | uspto-grants-2014_02 |