Methyl 3-oxo-7,11,15-trimethylhexadeca-6,10,14-trienoate → [2-Hydroxy-6,10,14-trimethylpentadeca-5,9,13-trienyl]phosphonic acid

HRID 2379524

反応式

HRID 2379524 の反応式
O=C(CCC=C(C)CCC=C(C)CCC=C(C)C)CC(OC)=O.[O:24]=[C:25]([CH2:33][CH2:34][CH:35]=[C:36]([CH3:48])[CH2:37][CH2:38][CH:39]=[C:40]([CH3:47])[CH2:41][CH2:42][CH:43]=[C:44]([CH3:46])[CH3:45])[CH2:26][P:27](=[O:32])([O:30]C)[O:28]C>>[OH:24][CH:25]([CH2:33][CH2:34][CH:35]=[C:36]([CH3:48])[CH2:37][CH2:38][CH:39]=[C:40]([CH3:47])[CH2:41][CH2:42][CH:43]=[C:44]([CH3:46])[CH3:45])[CH2:26][P:27](=[O:28])([OH:32])[OH:30]

参加物

3

反応物 2

HCID 54245426Methyl 3-oxo-7,11,15-trimethylhexadeca-6,10,14-trienoateHCID 54462394Dimethyl [2-oxo-6,10,14-trimethylpentadeca-5,9,13-trienyl]phosphonate

生成物 1

HCID 54248241[2-Hydroxy-6,10,14-trimethylpentadeca-5,9,13-trienyl]phosphonic acid

実験手順

This compound was prepared similarly by the method described in Step 2 of Example 1 except that methyl 3-oxo-7,11,15-trimethylhexadeca-6,10,14-trienoate was replaced by dimethyl [2-oxo-6,10,14-trimethyl-pentadeca-5,9,13-trienyl]phosphonate and the product from this reaction was used in the hydrolysis step similarly to the method used in Step 2 in Example 2 to give, after lyophilization, title compound as a nearly colorless gum.

後処理

  1. customThis compound was prepared similarly by the method
  2. customthe product from this reaction was used in the hydrolysis step similarly to the method
  3. customto give

出典と根拠

ORDレコード
ord-6bd5426d102d42cca2c0e0acaf3da6d3
出典データセット
uspto-grants-1994_11
特許番号
US05362906

関連ノート

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