Hydrazine → Tridecanoic acid hydrazide

HRID 2380530ノート

反応式

HRID 2380530 の反応式
[C:1]([O:15]C)(=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13].[NH2:17][NH2:18]>C(O)C>[C:1]([NH:17][NH2:18])(=[O:15])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13]

参加物

4

反応物 2

HCID 9321HydrazineHCID 15608Methyl tridecanoate

生成物 1

HCID 10823265Tridecanoic acid hydrazide

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

実験手順

A solution of tridecanoic acid, methyl ester (24.63 g, 0.1078 mol), and anhydrous hydrazine (3.40 mL, 0.108 mol) in absolute ethanol (150 mL) was stirred at room temperature for 24 hours, then refluxed 2 days. The solution was allowed to cool, and the solid that crystallized was filtered off, washed, and dried in vacuo; yield 18.6 g (75%); mp 101°-104° C.

後処理

  1. temperaturerefluxed 2 days
  2. temperatureto cool
  3. customthe solid that crystallized
  4. filtrationwas filtered off
  5. washwashed
  6. customdried in vacuo

出典と根拠

ORDレコード
ord-372b753926ac47e38a83d25bbc72ef98
出典データセット
uspto-grants-1994_11
特許番号
US05366987

反応ノート

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