N-Hydroxyphthalimide → Hydroperoxide, phenylmethyl
反応式
ON1C(=O)[C:5]2=[CH:8][CH:9]=[CH:10][CH:11]=[C:4]2[C:3]1=[O:12].[O-:13]O.C1(C(C)C)C=CC=CC=1>C1(C)C=CC=CC=1>[CH2:3]([O:12][OH:13])[C:4]1[CH:5]=[CH:8][CH:9]=[CH:10][CH:11]=1参加物
4
実験手順
0.3 mmol of N-hydroxyphthalimide and 0.6 mmol of cumene hydroperoxide are added at a temperature of 125° C. to 30 mmol of toluene in a round-bottomed flask having an attached reflux condenser. The reaction mixture is stirred for 8 hours at said temperature under an oxygen atmosphere of 1 bar. Benzyl hydroperoxide is obtained at a selectivity of 51.7% at a toluene conversion rate of 8%. Other products are benzaldehyde (24.6%) and benzoic acid (23.6%).
後処理
- temperaturean attached reflux condenser
出典と根拠
- ORDレコード
- ord-7f450eba77dc4cb2b2f224ef056837d4
- 出典データセット
- uspto-grants-2005_02
- 特許番号
- US06852893B2
反応ノート
読み込み中…