Octanoic Acid → 2-Propylheptyl octanoate

HRID 238900ノート

反応式

HRID 238900 の反応式
[CH2:1]([CH:4]([CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:5][OH:6])[CH2:2][CH3:3].[C:12](O)(=[O:20])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19]>O>[C:12]([O:6][CH2:5][CH:4]([CH2:1][CH2:2][CH3:3])[CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])(=[O:20])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19]

参加物

4

反応物 2

HCID 379Octanoic AcidHCID 248472-Propyl-1-heptanol

生成物 1

HCID 118553392-Propylheptyl octanoate収率 99.3%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

158.3 g 2-propylheptanol (1 mol) and 144.2 g caprylic acid (1 mol) were heated for 5 h to 220° C. on a water separator together with 0.30 g Fascat® 2001 (Sn oxalate: 0.1% by weight, based on the composition as a whole). After the separation of water had stopped, the crude product was distilled in an oil pump vacuum through a 250 mm Vigreux column (T=92-94° C.). 282.4 g of a colorless oil were obtained: OHV=<1, AV=<0.1.

後処理

  1. customAfter the separation of water
  2. distillationthe crude product was distilled in an oil pump vacuum through a 250 mm Vigreux column (T=92-94° C.)

出典と根拠

ORDレコード
ord-fa57d1b434f5450d9998fc11a17378e2
出典データセット
uspto-grants-2014_02
特許番号
US08642652B2

反応ノート

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