Benzene, 1-chloro-4-(propylsulfonyl)- → 2-Bromo-1-chloro-4-(propylsulfonyl)benzene

反応式

[Br:1][C:2]1[CH:7]=[C:6]([S:8]([CH2:11][CH2:12][CH3:13])(=[O:10])=[O:9])[CH:5]=[CH:4][C:3]=1F.[Cl:15]C1C=CC(S(CCC)(=O)=O)=CC=1>>[Br:1][C:2]1[CH:7]=[C:6]([S:8]([CH2:11][CH2:12][CH3:13])(=[O:10])=[O:9])[CH:5]=[CH:4][C:3]=1[Cl:15]

参加物

反応物 2

HCID 21041456Benzene, 1-chloro-4-(propylsulfonyl)-2 回

HCID 585220712-Bromo-1-fluoro-4-(propylsulfonyl)benzene

生成物 1

HCID 585220882-Bromo-1-chloro-4-(propylsulfonyl)benzene収率 86%

実験手順

Following the general method as outlined in Intermediate 106, starting from 1-chloro-4-(propylsulfonyl)benzene (Intermediate 125), the title compound was obtained as an oil which solidified upon standing in 86% yield.

出典と根拠

ORDレコード: ord-0d4bbb0cbcce4c0880f6f4a27f376e3b
出典データセット: uspto-grants-2012_09
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US08273769B2

反応ノート

読み込み中…