192870-97-6 → HCID 18980462、化合物

HRID 2392750ノート

反応式

HRID 2392750 の反応式
[ClH:1].[CH3:2][N:3]([CH2:5][CH:6]1[CH2:11][CH:10]([O:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)[CH2:9][CH2:8][C:7]1=[O:19])[CH3:4].Br[C:21]1[CH:26]=[CH:25][CH:24]=[C:23]([O:27][CH2:28][C:29]([CH3:31])=[CH2:30])[CH:22]=1>>[ClH:1].[CH3:4][N:3]([CH2:5][CH:6]1[CH2:11][CH:10]([O:12][C:13]2[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=2)[CH2:9][CH2:8][C:7]1([C:21]1[CH:26]=[CH:25][CH:24]=[C:23]([O:27][CH2:28][C:29]([CH3:31])=[CH2:30])[CH:22]=1)[OH:19])[CH3:2]

参加物

3

反応物 2

HCID 15816719192870-97-6HCID 18980453HCID 18980453、化合物

生成物 1

HCID 18980462HCID 18980462、化合物収率 51%

実験手順

The base of compound (27) was reacted with 1-bromo-3-(2-methyl-allyloxy)-benzene corresponding to the conditions described in Example 1. The base obtained was purified with ether via a silica gel column and was taken up in 2-butanone. After adding trimethylchlorosilane/water, compound (31) was obtained in a yield of 51% theoretical. melting point: 193° C.-195° C.

後処理

  1. customThe base obtained
  2. customwas purified with ether via a silica gel column
  3. additionAfter adding trimethylchlorosilane/water

出典と根拠

ORDレコード
ord-567e1ae6289e4e6fa33cf391c613d585
出典データセット
uspto-grants-1998_09
特許番号
US05801201

反応ノート

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