関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 4,6-Diphenyl-2-pyridone | HCID 3846201 | — |
| 反応物 | Ethyl 6-bromo-2-ethyl-2-methylhexanoate | HCID 18987177 | — |
| 触媒 | HCID 178418647 | HCID 178418647 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | Ethyl 2-ethyl-2-methyl-6-[(4,6-diphenyl-2-pyridyl)oxy]hexanoate | HCID 18987342 | — |
反応手順
The procedure in Example 5 is followed but using 4,6-diphenyl-2-pyridinone (3 g), ethyl 6-bromo-2-ethyl-2-methylhexanoate (6.44 g) [prepared according to the method of K. E. MOELLER, Brenstoff-Chem., 47, 10 (1966)], silver carbonate (1.68 g) and dimethylformamide (110 cc). The reaction mixture is heated at 100° C. for 121 hours. The product is purified by chromatography under pressure on silica gel (30-60 mm; eluent: n-hexane-ethyl acetate 9-1). (yellow oil)
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 特許番号 | US05492915 |
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| 出典データセット | uspto-grants-1996_02 |
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| ORD ID | ord-2c8b01799b8b44a08d6319ec5c3aaf18 |
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| 出典メモ | uspto-grants-1996_02 |
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