N,N'-Dibutyl-1,6-hexanediamine → N,N'-(1,6-hexylene)-bis[N-butyl-2-hydroxyundecylamine]

反応式

[CH2:1]1[O:12][CH:2]1[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[CH2:13]([NH:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][NH:24][CH2:25][CH2:26][CH2:27][CH3:28])[CH2:14][CH2:15][CH3:16]>>[CH2:18]([N:17]([CH2:1][CH:2]([OH:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:13][CH2:14][CH2:15][CH3:16])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][N:24]([CH2:1][CH:2]([OH:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:25][CH2:26][CH2:27][CH3:28]

参加物

反応物 2

HCID 20972N,N'-Dibutyl-1,6-hexanediamine

HCID 5377372-Nonyloxirane

生成物 1

HCID 21332430N,N'-(1,6-hexylene)-bis[N-butyl-2-hydroxyundecylamine]

実験手順

Condensation of 1-undecene oxide and N,N'-dibutylhexamethylenediamine affords N,N'-(1,6-hexylene)-bis[N-butyl-2-hydroxyundecylamine] (I: R= CH3 (CH2)8, R' = CH3 (CH2)3, X= (CH2)6, Z= H).

出典と根拠

ORDレコード: ord-d98a197885fc4be59416d07ab5f2696f
出典データセット: uspto-grants-1977_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04022833

反応ノート

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