関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 4-Sulfophthalic acid | HCID 6962 | — |
| 反応物 | Phosphorus oxychloride | HCID 24813 | — |
| 反応物 | 1,8-Diaminonaphthalene | HCID 68067 | — |
| 反応物 | Sulphophthaloperinone | HCID 21434658 | — |
| 溶媒 | O-Xylene | HCID 7237 | — |
| 溶媒 | N-methyl-2-pyrrolidone | HCID 13387 | — |
| 生成物 | Phthaloperinone sulphochloride | HCID 86734752 | 91.4% |
反応手順
11.5 g of sulphophthaloperinone, prepared from 4-sulphophthalic acid and 1,8-naphthylenediamine in N-methylpyrrolidone, are suspended in 100 ml of xylene. 9.2 g of phosphorus oxychloride are added and the mixture is heated to 80° C for 6 - 7 hours, whilst stirring. 25 - 30 ml of xylene are then distilled off under reduced pressure and after cooling the reaction product which has precipitated is filtered off and the residue is rinsed with petroleum ether. 11.6 g of phthaloperinone-sulphochloride are obtained.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 特許番号 | US04024144 |
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| 出典データセット | uspto-grants-1977_05 |
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| ORD ID | ord-81a6fe1d67a5465a8a61445368ca5662 |
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| 出典メモ | uspto-grants-1977_05 |
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