Ammonia → HCID 21432595、化合物
反応式
[N+:1]([C:4]1[CH:5]=[C:6]([CH:14]=[CH:15][C:16]=1Cl)[C:7]([C:9]1[S:10][CH:11]=[CH:12][N:13]=1)=[O:8])([O-:3])=[O:2].[NH3:18]>C(O)C>[N+:1]([C:4]1[CH:5]=[C:6]([CH:14]=[CH:15][C:16]=1[NH2:18])[C:7]([C:9]1[S:10][CH:11]=[CH:12][N:13]=1)=[O:8])([O-:3])=[O:2]参加物
4
実験手順
A suspension of 63 g. (0.24 mol) of 2-(3-nitro-4-chlorobenzoyl)thiazole in 3 liters of a saturated solution of ammonia in ethanol was autoclaved at 100° C. for 24 hrs. The mixture was concentrated in vacuo and the resulting residue dissolved in 1.5 liters of warm 5N hydrochloric acid. The solution was cooled to room temperature and neutralized with concentrated ammonium hydroxide to yield 2-(3-nitro-4-aminobenzoyl)thiazole as yellow-orange prisms, mp. 179°-181° C. (methanol).
後処理
- additionA suspension of 63 g
- concentrationThe mixture was concentrated in vacuo
- dissolutionthe resulting residue dissolved in 1.5 liters of warm 5N hydrochloric acid
出典と根拠
- ORDレコード
- ord-1ed5b9e8c4354461a421159f2c733286
- 出典データセット
- uspto-grants-1977_05
- 特許番号
- US04026936
反応ノート
読み込み中…