Sulfur → Ethyl (7-methoxynaphthalen-1-yl)acetate

HRID 2399388ノート

反応式

HRID 2399388 の反応式
[CH3:1][O:2][C:3]1[CH:12]=[C:11]2[C:6]([CH2:7][CH2:8][CH2:9][C:10]2=[CH:13][C:14]([O:16][CH2:17][CH3:18])=[O:15])=[CH:5][CH:4]=1.[S]>C(OCC)(=O)C>[CH3:1][O:2][C:3]1[CH:12]=[C:11]2[C:6]([CH:7]=[CH:8][CH:9]=[C:10]2[CH2:13][C:14]([O:16][CH2:17][CH3:18])=[O:15])=[CH:5][CH:4]=1

参加物

4

反応物 2

HCID 5362487SulfurHCID 53884445Ethyl (7-methoxy-1,2,3,4-tetrahydro-1-naphthylidene)acetate

生成物 1

HCID 13570063Ethyl (7-methoxynaphthalen-1-yl)acetate

試薬・触媒・溶媒 1

HCID 8857Ethyl Acetate溶媒

反応条件

温度
215 °C

実験手順

50 g of ethyl 7-methoxy-1,2,3,4-tetrahydro-1-naphthylideneacetate are mixed with 7.35 g of sulphur, and the mixture is heated at 215° C. for 10 hours. It is cooled, 300 cm3 of ethyl acetate are added, and the mixture is stirred for 30 minutes and filtered. It is then dried. The resulting residue is used as such for the hydrolysis step.

後処理

  1. temperatureIt is cooled
  2. filtrationfiltered
  3. customIt is then dried
  4. customsuch for the hydrolysis step

出典と根拠

ORDレコード
ord-b54f9ef2b56a45b5a86f92bab004d701
出典データセット
uspto-grants-1995_09
特許番号
US05449690

反応ノート

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