化工社化工社 化学情報印刷レポート · 研究参考用
Tempo → ADONA
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Tempo | HCID 2724126 | — |
| 反応物 | 1,1,3-Trihydro-4,8-dioxaperfluorononanol | HCID 86668230 | — |
| 反応物 | HCID 178418247 | HCID 178418247 | — |
| 触媒 | Cobaltous nitrate hexahydrate | HCID 24821 | — |
| 触媒 | Manganese nitrate tetrahydrate | HCID 182616 | — |
| 溶媒 | Acetic Acid | HCID 176 | — |
| 生成物 | ADONA | HCID 52915299 | 70.6% |
反応手順
50 mL of acetic acid, 0.137 g of manganese nitrate tetrahydrate, 0.159 g of cobalt nitrate hexahydrate, TEMPO (0.42 g), CH3CO2Na (2.24 g) and 10 g of 2,2,3-trifluoro-3-(1,1,2,2,3,3-hexafluoro-3-trifluoromethoxy-propoxy)-propan-1-ol were placed in a reaction vessel as described in example 17 except that a 100 mL vessel instead of a 200 mL vessel was used. The reaction was carried out and worked up as described in example 9. Distillation gave 7.29 g of acid (1.6 mmHg, 58° C.). Yield: 70%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08809580B2 |
| 出典データセット | uspto-grants-2014_08 |
| ORD ID | ord-516ce911e58946cf9feb52b0e052555f |
| 出典メモ | uspto-grants-2014_08 |