2-Propanone, 1-bromo-3-(4-nitrophenyl)- → HCID 13093759、化合物
反応式
Br[CH2:2][C:3]([CH2:5][C:6]1[CH:11]=[CH:10][C:9]([N+:12]([O-:14])=[O:13])=[CH:8][CH:7]=1)=[O:4].[C:15]1(=[O:25])[NH:19][C:18](=[O:20])[C:17]2=[CH:21][CH:22]=[CH:23][CH:24]=[C:16]12.[K]>C1(C)C=CC=CC=1>[C:15]1(=[O:25])[N:19]([CH2:2][C:3]([CH2:5][C:6]2[CH:11]=[CH:10][C:9]([N+:12]([O-:14])=[O:13])=[CH:8][CH:7]=2)=[O:4])[C:18](=[O:20])[C:17]2=[CH:21][CH:22]=[CH:23][CH:24]=[C:16]12参加物
4
実験手順
A mixture of 1-bromo-3-(4-nitrophenyl)acetone and potassium phthalimide (7.2 g.) in toluene (100 ml.) was heated under reflux with stirring for 4 hours. The mixture was filtered, the filtrate evaporated. The residue was purified by chromatography on silica gel using CH2Cl2 as eluant to give 1-phthalimido-3-(4-nitrophenyl)acetone, m.p. 184°.