Potassium Carbonate → 9-Decenyl bis(pentafluoroethyl)phosphinite

HRID 241314

反応式

HRID 241314 の反応式
[CH2:1]([OH:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH:9]=[CH2:10].C([O-])([O-])=O.[K+].[K+].[F:18][C:19]([P:25](Cl)[C:26]([F:32])([F:31])[C:27]([F:30])([F:29])[F:28])([F:24])[C:20]([F:23])([F:22])[F:21]>C(Cl)Cl>[F:24][C:19]([P:25]([C:26]([F:31])([F:32])[C:27]([F:28])([F:29])[F:30])[O:11][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH:9]=[CH2:10])([F:18])[C:20]([F:23])([F:22])[F:21]

参加物

5

反応物 3

HCID 11430Potassium CarbonateHCID 256129-Decen-1-olHCID 2757428Bis(pentafluoroethyl)phosphinous chloride2 回

生成物 1

HCID 866538149-Decenyl bis(pentafluoroethyl)phosphinite

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

0.31 g (1.9 mmol) of 9-decen-1-ol is initially introduced in CH2Cl2 with excess K2CO3, and 0.64 g (2.1 mmol) of bis(pentafluoroethyl)phosphinous acid chloride, (C2F5)2PCl, is condensed in. After the mixture has been stirred at room temperature for 30 minutes, the precipitate is filtered off, and volatile substances are removed in vacuo. The product, 9-decenyl bis(pentafluoroethyl)phosphinite, remains as a colourless, oily liquid, which is characterised by spectroscopy.

後処理

  1. customcondensed in
  2. filtrationthe precipitate is filtered off
  3. customvolatile substances are removed in vacuo

出典と根拠

ORDレコード
ord-c98278044eb643478b8fe43038cd321c
出典データセット
uspto-grants-2014_02
特許番号
US08648202B2

関連ノート

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