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m-Chloroperbenzoic acid → 3-methylsulfinyl-N'-sulfamoylpropanimidamide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | m-Chloroperbenzoic acid | HCID 70297 | — |
| 反応物 | HCID 178503794 | HCID 178503794 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 溶媒 | Chloroform | HCID 6212 | — |
| 生成物 | 3-methylsulfinyl-N'-sulfamoylpropanimidamide | HCID 178504640 | — |
反応手順
A solution of commercial 80% pure m-chloroperbenzoic acid (5.4 g, 25 mmol) in chloroform (40 ml) was added dropwise to a solution of N-sulfamyl-3-(methylthio)propionamidine (4.94 g, 25 mmol) in methanol (50 ml) at room temperature. After stirring for two hours, the product was collected by filtration, analytically pure, to give 4.44 g, mp 141°-144°.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04496737 |
| 出典データセット | uspto-grants-1985_01 |
| ORD ID | ord-461e854f44064aca83215e2c4ef6b828 |
| 出典メモ | uspto-grants-1985_01 |