Sodium Methoxide → HCID 54496620、化合物

HRID 2413449ノート

反応式

HRID 2413449 の反応式
C[O-].[Na+].[Cl:4][C:5]1[CH:6]=[N:7][C:8]2[C:13]([CH:14]=1)=[CH:12][CH:11]=[C:10]([Cl:15])[C:9]=2[CH:16]=O>CO.C(O)C>[Cl:4][C:5]1[CH:6]=[N:7][C:8]2[C:13]([CH:14]=1)=[CH:12][CH:11]=[C:10]([Cl:15])[C:9]=2[CH:16]=[CH:16][C:9]1[C:10]([Cl:15])=[CH:11][CH:12]=[C:13]2[C:8]=1[N:7]=[CH:6][C:5]([Cl:4])=[CH:14]2

参加物

5

反応物 2

HCID 10942334Sodium MethoxideHCID 13090787HCID 13090787、化合物

生成物 1

HCID 54496620HCID 54496620、化合物

試薬・触媒・溶媒 2

HCID 702Ethanol溶媒HCID 887Methanol溶媒

実験手順

18 ml of a 15% strength solution of sodium methylate in methanol were added dropwise, at room temperature, to a suspension of 25.4 g of 3,7-dichloro-8-triphenylphosphoniummethylquinoline chloride and 11.3 g of 3,7-dichloro-8-formylquinoline in 150 ml of ethanol. The mixture was stirred for 2 hours, after which the yellow precipitate was filtered off under suction, treated with water and again filtered off under suction.

後処理

  1. filtrationafter which the yellow precipitate was filtered off under suction
  2. additiontreated with water
  3. filtrationagain filtered off under suction

出典と根拠

ORDレコード
ord-8841b6b409c7485da9c83fc3053ea8a7
出典データセット
uspto-grants-1988_01
特許番号
US04717416

反応ノート

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