Sulfuric Acid → HCID 13090787、化合物

HRID 2413452ノート

反応式

HRID 2413452 の反応式
[Cl:1][C:2]1[CH:3]=[N:4][C:5]2[C:10]([CH:11]=1)=[CH:9][CH:8]=[C:7]([Cl:12])[C:6]=2[CH:13](Cl)Cl.S(=O)(=O)(O)[OH:17]>>[Cl:1][C:2]1[CH:3]=[N:4][C:5]2[C:10]([CH:11]=1)=[CH:9][CH:8]=[C:7]([Cl:12])[C:6]=2[CH:13]=[O:17]

参加物

3

反応物 2

HCID 1118Sulfuric AcidHCID 130907853,7-Dichloro-8-(dichloromethyl)quinoline

生成物 1

HCID 13090787HCID 13090787、化合物収率 87%

実験手順

56 parts of 3,7-dichloro-8-dichloromethylquinoline in 250 parts of 90% strength sulfuric acid were stirred for 6 hours at 100° C. The solution was cooled and then poured onto ice, and the precipitated solid was filtered off under suction, washed neutral with water and dried to give 39 parts (87% of theory) of 3,7-dichloroquinoline-8-carbaldehyde of melting point 208° C.

後処理

  1. temperatureThe solution was cooled
  2. additionpoured onto ice
  3. filtrationthe precipitated solid was filtered off under suction
  4. washwashed neutral with water
  5. customdried

出典と根拠

ORDレコード
ord-40b74716aa4d4f9cace4b06928df461b
出典データセット
uspto-grants-1988_01
特許番号
US04717416

反応ノート

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