HCID 70410054、化合物 → cis-3-(4-Acetyl-3-hydroxy-2-propyl-phenoxy)-1-(4-carbomethoxy methyl-2-bromo phenoxy)cyclohexane

反応式

[C:1]([C:4]1[CH:28]=[CH:27][C:7]([O:8][C@H:9]2[CH2:14][CH2:13][CH2:12][C@H:11]([O:15][C:16]3[CH:21]=[CH:20][C:19]([CH2:22][C:23]([OH:25])=[O:24])=[CH:18][C:17]=3[Br:26])[CH2:10]2)=[C:6]([CH2:29][CH2:30][CH3:31])[C:5]=1[OH:32])(=[O:3])[CH3:2].[C:33](C1C=CC(O[C@@H]2CCC[C@H](OS(C)(=O)=O)C2)=C(CCC)C=1O)(=O)C>>[C:1]([C:4]1[CH:28]=[CH:27][C:7]([O:8][C@@H:9]2[CH2:14][CH2:13][CH2:12][C@H:11]([O:15][C:16]3[CH:21]=[CH:20][C:19]([CH2:22][C:23]([O:25][CH3:33])=[O:24])=[CH:18][C:17]=3[Br:26])[CH2:10]2)=[C:6]([CH2:29][CH2:30][CH3:31])[C:5]=1[OH:32])(=[O:3])[CH3:2]

参加物

反応物 2

HCID 70410054HCID 70410054、化合物

HCID 88643326HCID 88643326、化合物

生成物 1

HCID 70409901cis-3-(4-Acetyl-3-hydroxy-2-propyl-phenoxy)-1-(4-carbomethoxy methyl-2-bromo phenoxy)cyclohexane

実験手順

By following Step E of Example 8, but substituting the title compound of Step D of Example 8 for the title compound of Step C of Example 8, the title compound of this step was obtained as an oil.

出典と根拠

ORDレコード: ord-7853ff48f31b430e89e9eb774a0a6b99
出典データセット: uspto-grants-1988_01
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04720505

反応ノート

読み込み中…