Triethyl phosphite → 1-(Diethylphosphono)-6-(nonafluorobutyl)hexane
反応式
Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][C:8]([F:20])([F:19])[C:9]([F:18])([F:17])[C:10]([F:16])([F:15])[C:11]([F:14])([F:13])[F:12].[P:21]([O:28]CC)([O:25][CH2:26][CH3:27])[O:22][CH2:23][CH3:24]>>[CH2:23]([O:22][P:21]([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][C:8]([F:20])([F:19])[C:9]([F:18])([F:17])[C:10]([F:16])([F:15])[C:11]([F:14])([F:13])[F:12])([O:25][CH2:26][CH3:27])=[O:28])[CH3:24]参加物
3
反応条件
- 温度
- 150 °C
実験手順
A mixture of 18.04 g of 1-bromo-6-(nonafluorobutyl)hexane and 19.6 g of triethyl phosphite was heated at 150° C. After 18 hr, an additional 10.0 g of triethyl phosphite was added, and heating was continued for 8 hr more. Diethyl ethylphosphonate and other volatiles were removed by distillation, b.p. 30-50° C. at 0.05 torr (7 Pa), and bulb-to-bulb distillation of the concentrate provided 18.88 g of 1-(diethylphosphono)-6-(nonafluorobutyl)hexane as a clear, colorless liquid, b.p. 120-130° C. at 0.05 torr (7 Pa).