Triethyl phosphite → HCID 22630503、化合物
反応式
Br[CH2:2][CH2:3][CH2:4][CH2:5][C:6]([F:18])([F:17])[C:7]([F:16])([F:15])[C:8]([F:14])([F:13])[C:9]([F:12])([F:11])[F:10].[P:19]([O:26]CC)([O:23][CH2:24][CH3:25])[O:20][CH2:21][CH3:22]>>[CH2:21]([O:20][P:19]([CH2:2][CH2:3][CH2:4][CH2:5][C:6]([F:18])([F:17])[C:7]([F:16])([F:15])[C:8]([F:14])([F:13])[C:9]([F:12])([F:11])[F:10])([O:23][CH2:24][CH3:25])=[O:26])[CH3:22]参加物
3
反応条件
- 温度
- 150 °C
実験手順
A mixture of 12.40 g of 1-bromo-4-(nonafluorobutyl)butane and 21.00 g of triethyl phosphite was heated at 150° C. After 18 hr, diethyl ethylphosphonate and other volatiles were removed from the mixture by distillation, b.p. 30-50° C. at 0.05 torr (7 Pa). Bulb-to-bulb distillation of the remaining concentrated mixture provided 13.0 g of 1-(diethylphosphono)-4-(nonafluorobutyl)butane as a clear, colorless liquid, b.p. 105-110° C. at 0.05 torr (7 Pa).
後処理
- customdiethyl ethylphosphonate and other volatiles were removed from the mixture by distillation, b.p. 30-50° C. at 0.05 torr (7 Pa)