Sulfuryl chloride → Diphenethylphosphinylchloride

HRID 2418526ノート

反応式

HRID 2418526 の反応式
[CH2:1]([P:9]([CH2:12][CH2:13][C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1)(=O)[OH:10])[CH2:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.S(Cl)([Cl:23])(=O)=O>C(Cl)(Cl)(Cl)Cl>[CH2:1]([P:9]([Cl:23])([CH2:12][CH2:13][C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1)=[O:10])[CH2:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

参加物

4

反応物 2

HCID 24648Sulfuryl chlorideHCID 15121925Bis(2-phenylethyl)phosphinic acid

生成物 1

HCID 23320628Diphenethylphosphinylchloride

試薬・触媒・溶媒 1

HCID 5943Carbon Tetrachloride溶媒

実験手順

Diphenethylphosphinic acid (1.67 g, 6.1 m mole) was dissolved in carbon tetrachloride (5 ml), and sulfuryl chloride (1.46 g, 10.8 ml) was added thereto, and the mixture was heated while refluxing for 2 hours. It was confirmed that the starting material did not remain by tracement of the NMR spectrum. The solvent and excess sulfuryl chloride were distilled off under reduced pressure to obtain an oily diphenethylphosphinylchloride, which was supplied for the following reaction.

後処理

  1. temperaturethe mixture was heated
  2. temperaturewhile refluxing for 2 hours
  3. distillationThe solvent and excess sulfuryl chloride were distilled off under reduced pressure

出典と根拠

ORDレコード
ord-985d388dda5d436d8e36c911f11dbe54
出典データセット
uspto-grants-1984_09
特許番号
US04472381

反応ノート

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