3,7-Dihydro-3,7-dimethyl-1-(5-oxohexyl)-1H-Purine-2,6-dione → 1-(5-Oxohexyl)-3,7-dimethyl-8-(trifluoromethyl)-1,2,3,6-tetrahydro-7H-purine-2,6-dione

HRID 2418910

反応式

HRID 2418910 の反応式
CC(=O)CCCCn1c(=O)c2c(ncn2C)n(C)c1=O.O=S(O)C(F)(F)F.[Zn]>CC(C)(C)OO.Fc1c(F)c(F)c(C(F)(F)F)c(F)c1F.O>CC(=O)CCCCn1c(=O)c2c(nc(C(F)(F)F)n2C)n(C)c1=O

参加物

6

反応物 2

HCID 47403,7-Dihydro-3,7-dimethyl-1-(5-oxohexyl)-1H-Purine-2,6-dioneHCID 89601280CID 89601280

生成物 1

HCID 1018761991-(5-Oxohexyl)-3,7-dimethyl-8-(trifluoromethyl)-1,2,3,6-tetrahydro-7H-purine-2,6-dione収率 79%

試薬・触媒・溶媒 3

HCID 6410tert-Butyl hydroperoxide試薬HCID 962Water溶媒HCID 9906Octafluorotoluene溶媒

反応条件

温度
25 °C

出典と根拠

ORDレコード
ord-aff7dcedb0bd47c1bdd70b0572644e6a
出典データセット
Minisci dataset from Roche

関連ノート

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