2-Imidazolidinone, 1-(p-chlorophenyl)- → HCID 20315721、化合物

HRID 2419455ノート

反応式

HRID 2419455 の反応式
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([N:8]2[CH2:12][CH2:11][NH:10][C:9]2=[O:13])=[CH:4][CH:3]=1.[N:14]([O-])=[O:15].[Na+]>C(O)(=O)C.O>[Cl:1][C:2]1[CH:3]=[CH:4][C:5]([N:8]2[CH2:12][CH2:11][N:10]([N:14]=[O:15])[C:9]2=[O:13])=[CH:6][CH:7]=1

参加物

5

反応物 2

HCID 264512-Imidazolidinone, 1-(p-chlorophenyl)-HCID 23668193Sodium Nitrite

生成物 1

HCID 20315721HCID 20315721、化合物

試薬・触媒・溶媒 2

HCID 176Acetic Acid溶媒HCID 962Water溶媒3 回

実験手順

In a solution of glacial acetic acid (2750 ml) and water (250 ml) was dissolved 150 g (0.75 mol) of 1-(4-chlorophenyl)-2-imidazolidinone with heating. The solution was cooled to room temperature, and sodium nitrite (70 g, 1.0 mol) in water (200 ml) was added dropwise over 1 hr. The mixture was stirred for another 6 hrs, diluted with water (1.5 l) and the product (137 g, 81%) was collected m.p. 154°-156°.

後処理

  1. temperaturewith heating
  2. customthe product (137 g, 81%) was collected m.p. 154°-156°

出典と根拠

ORDレコード
ord-087ddd5c60cb4049a1b0540e9fe6ed35
出典データセット
uspto-grants-1978_08
特許番号
US04105850

反応ノート

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