HCID 678044、化合物 → Phenylsulphonylacetonitrile
反応式
C(NC1SC=C(C2C=CC=CC=2)C=1C(OCC)=O)(=O)C.C([NH:24][C:25]1SC=C[C:29]=1[S:30]([C:33]1[CH:38]=[CH:37][CH:36]=[CH:35][CH:34]=1)(=[O:32])=[O:31])(=O)C>>[C:33]1([S:30]([CH2:29][C:25]#[N:24])(=[O:31])=[O:32])[CH:34]=[CH:35][CH:36]=[CH:37][CH:38]=1参加物
3
実験手順
In place of the 2-acetylamino-3-ethoxycarbonyl-4-phenylthiophene used in Example 4 there is used an equivalent amount of 2-acetylamino-3-phenylsulphonylthiophene (which was obtained by condensing phenylsulphonylacetonitrile with 2:5-dihydroxy-1:4-dithiane in ethanol containing piperidine and subsequently acetylating) whereby 2-amino-3-phenylsulphonyl-5-nitrothiophene (m.pt 155° - 157° C) is obtained.
出典と根拠
- ORDレコード
- ord-cc437a27e1804065875a2b53aeac497a
- 出典データセット
- uspto-grants-1978_08
- 特許番号
- US04108867
反応ノート
読み込み中…