Dimethyldioxirane → 8-Benzyloxy-3-methyl5-oxiranyl-1H-quinolin-2-one
反応式
[CH2:1]([O:8][C:9]1[CH:10]=[CH:11][C:12]([CH:21]=[CH2:22])=[C:13]2[C:18]=1[NH:17][C:16](=[O:19])[C:15]([CH3:20])=[CH:14]2)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.CC1(C)O[O:25]1>CC(C)=O>[CH2:1]([O:8][C:9]1[CH:10]=[CH:11][C:12]([CH:21]2[CH2:22][O:25]2)=[C:13]2[C:18]=1[NH:17][C:16](=[O:19])[C:15]([CH3:20])=[CH:14]2)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1参加物
4
実験手順
To 8-benzyloxy-3-methyl-5-vinyl-1H-quinolin-2-one (300 mg) is added to a 0.1M solution of dimethyldioxirane in acetone (12.4 mL). After stirring at room temperature for 2 hours, the solvent is removed in vacuo to yield the product.
後処理
- customthe solvent is removed in vacuo
- customto yield the product
出典と根拠
- ORDレコード
- ord-024d87e41e5148058d65a29ff234a912
- 出典データセット
- uspto-grants-2014_02
- 特許番号
- US08658673B2
反応ノート
読み込み中…