関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Ethylene carbonate | HCID 7303 | — |
| 反応物 | Jeffamine | HCID 15131492 | — |
| 触媒 | Sodium Stannate | HCID 21977542 | — |
| 生成物 | Carbon Dioxide | HCID 280 | 11.1% |
| 生成物 | Ethylene carbonate | HCID 7303 | 96% |
反応手順
A 10:1 mole ratio of ethylene carbonate to aminated poly(propylene glycol) (Jeffamine D-400, Mw=430, a product of the Jefferson Chemical Division of Texaco) is heated with stirring under a nitrogen atmosphere for 19 hours at 135° C. using 0.5 percent sodium stannate trihydrate as catalyst to give 96 percent ethylene carbonate conversion to a poly(alkylene carbonate) polyol with 11.1 percent carbon dioxide. The catalyst is removed in Example 1.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04709069 |
|---|
| 出典データセット | uspto-grants-1987_11 |
|---|
| ORD ID | ord-3f5818ac9ab54d41a134f1ff0c2dba2a |
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| 出典メモ | uspto-grants-1987_11 |
|---|
