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Sodium Hydroxide → 3-Phenoxybenzyl alcohol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Sodium Hydroxide | HCID 14798 | — |
| 反応物 | Benzenemethanol, 3-phenoxy-, 1-acetate | HCID 170904 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | 3-Phenoxybenzyl alcohol | HCID 26295 | 95% |
反応手順
2.42 g. (0.01 mole) of 3-phenoxybenzyl acetate, 5 cm3. of methanol and 5 cm3. of 2N sodium hydroxide solution are refluxed for three hours. Then the methanol is distilled off and the organic phase is dissolved in 30 cm3. of methylene chloride, washed with 10 cm3. of 1N hydrochloric acid solution and 10 cm3. of water. 1.90 g. of 3-phenoxybenzyl alcohol are obtained. nD20 : 1.593, yield 95%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04709081 |
| 出典データセット | uspto-grants-1987_11 |
| ORD ID | ord-1a6f3bb1de714fc18ae39f93cc964184 |
| 出典メモ | uspto-grants-1987_11 |