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Hydrochloric Acid → 3-Phenoxybenzyl alcohol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hydrochloric Acid | HCID 313 | — |
| 反応物 | Benzenemethanol, 3-phenoxy-, 1-acetate | HCID 170904 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | 3-Phenoxybenzyl alcohol | HCID 26295 | 90% |
反応手順
2.42 g. (0.01 mole) of 3-phenoxybenzyl acetate, 5 cm3. of methanol and 5 cm3. of 2N hydrochloric acid solution are refluxed for three hours. Then the methanol is distilled off. The organic phase is dissolved in 30 cm3. of methylene chloride, washed with 10 cm3. of water, 10 cm3. of 1N sodium hydroxide solution and 10 cm3. of water then evaporated. 1.8 g. of 3-phenoxybenzyl alcohol are obtained. nD20 : 1.593, yield 90%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04709081 |
| 出典データセット | uspto-grants-1987_11 |
| ORD ID | ord-f90801a985d04be688f6c4e70178ce4b |
| 出典メモ | uspto-grants-1987_11 |