化工社化工社 化学情報印刷レポート · 研究参考用
6-Hydroxy-2-naphthoic acid → 1,1,1-Trifluorooctan-2-YL 6-hydroxynaphthalene-2-carboxylate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 6-Hydroxy-2-naphthoic acid | HCID 85557 | — |
| 反応物 | 2-Octanol, 1,1,1-trifluoro- | HCID 97804 | — |
| 触媒 | Sulfuric Acid | HCID 1118 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | 1,1,1-Trifluorooctan-2-YL 6-hydroxynaphthalene-2-carboxylate | HCID 15724811 | — |
反応手順
To a solution of 2-hydroxy-6-carboxynaphthalene (1 g) and optically active 1,1,1-trifluoro-2-octanol (1.1 g) in methylene chloride (50 ml) was added a few drops of conc. sulfuric acid and the mixture was refluxed under stirring for about two days.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05207947 |
| 出典データセット | uspto-grants-1993_05 |
| ORD ID | ord-43d063be546145bd9ec5526f7bbccb38 |
| 出典メモ | uspto-grants-1993_05 |