化工社化工社 化学情報印刷レポート · 研究参考用
1-Decanol → 2-n-Decyloxycarbonylnaphthalene-6-carboxylic acid chloride
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Decanol | HCID 8174 | — |
| 反応物 | Triethylamine | HCID 8471 | — |
| 反応物 | 2-Dimethylaminopyridine | HCID 21885 | — |
| 反応物 | 2,6-Naphthalenedicarbonyl dichloride | HCID 3485596 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | 2-n-Decyloxycarbonylnaphthalene-6-carboxylic acid chloride | HCID 54316020 | 56.3% |
反応手順
After a solution of n-decyl alcohol (0.5 g), naphthalene-2,6-dicarboxylic acid dichloride (0.6 g), and triethylamine (0.27 g) and a very small amount of dimethylaminopyridine in methylene chloride (50 ml) was stirred at room temperature overnight, the solution was distilled to remove the solvent, until the titled compound (about 0.5 g) was obtained.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05207947 |
| 出典データセット | uspto-grants-1993_05 |
| ORD ID | ord-75e52ba2a4e54b1da4dfeb4197a82b67 |
| 出典メモ | uspto-grants-1993_05 |