関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Trimethyl orthobeznoate | HCID 69720 | — |
| 反応物 | 1-Acetyl-5-nitroindolin-2-one | HCID 2839329 | — |
| 溶媒 | Acetic Anhydride | HCID 7918 | — |
| 生成物 | 1-Acetyl-3-(1-methoxy-1-phenyl-methylidene)-5-nitro-2-indolinone | HCID 54140155 | — |
反応手順
30.0 g (0.137 mol) of 1-acetyl-5-nitro-2-indolinone are dissolved in 200 ml of acetic anhydride and after the addition of 50.0 g (0.274 mol) of trimethyl orthobenzoate stirred for 3 hours at 100° C. After cooling it is evaporated down to half the quantity, diluted with ether/petroleum ether, the precipitate is suction filtered and dried.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06855710B2 |
|---|
| 出典データセット | uspto-grants-2005_02 |
|---|
| ORD ID | ord-9462538d776349bebad5c84c86b36c45 |
|---|
| 出典メモ | uspto-grants-2005_02 |
|---|
