化工社化工社 化学情報印刷レポート · 研究参考用
Methyl Acrylate → Methyl 3-[(2-thienylmethyl)thio]propanoate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methyl Acrylate | HCID 7294 | — |
| 反応物 | Piperidine | HCID 8082 | — |
| 反応物 | Benzyltrimethylammonium hydroxide | HCID 66854 | — |
| 反応物 | Thenyl mercaptan | HCID 80408 | — |
| 生成物 | Methyl 3-[(2-thienylmethyl)thio]propanoate | HCID 15225387 | — |
反応手順
A solution of 2-thiophenemethanethiol (12 grams), methylacrylate (7.94 grams), piperidine (3 mL) and N-benzyltrimethylammonium hydroxide (3 mL) was stirred for 16 hours at room temperature. The reaction mixture was distilled in vacuo to yield the desired title compound. Yield: 16.5 grams (83%). Bp: 140° C. at 1 mmHg.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05212169 |
| 出典データセット | uspto-grants-1993_05 |
| ORD ID | ord-9c6e7bf39f6f4949ae051db4b2cfae12 |
| 出典メモ | uspto-grants-1993_05 |