1-methoxy-N,N,N',N'-tetramethylmethylenediamine → HCID 57041370、化合物

HRID 249309

反応式

HRID 249309 の反応式
[C:1]1([C:7]([C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=2)([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)[N:8]2[CH2:13][CH2:12][C:11](=[O:14])[CH2:10][CH2:9]2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.CO[CH:29](N(C)C)[N:30]([CH3:32])[CH3:31]>>[CH3:29][N:30]([CH:32]=[C:9]1[CH2:10][C:11](=[O:14])[CH2:12][CH2:13][N:8]1[C:7]([C:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1)([C:15]1[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=1)[C:21]1[CH:22]=[CH:23][CH:24]=[CH:25][CH:26]=1)[CH3:31]

参加物

3

反応物 2

HCID 709081-methoxy-N,N,N',N'-tetramethylmethylenediamineHCID 27484141-Tritylpiperidin-4-one

生成物 1

HCID 57041370HCID 57041370、化合物収率 64%

実験手順

1-Triphenylmethyl-4-piperidone (0.239 g, 0.70 mmol) was added to methoxybis(dimethylamino)methane (1.75 ml) and the reaction mixture was stirred at 50° for sixteen hours. Volatiles were then removed in vacuo to provide a yellow solid, which was triturated with ether, and air dried to give the title product as a light yellow solid (0.179 g, 0.45 mmol, 64% yield).

後処理

  1. customVolatiles were then removed in vacuo
  2. customto provide a yellow solid, which
  3. customwas triturated with ether, and air
  4. customdried

出典と根拠

ORDレコード
ord-d3145a449e0943ad99bd738ddbac25bb
出典データセット
uspto-grants-1993_05
特許番号
US05214051

関連ノート

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