化工社化工社 化学情報印刷レポート · 研究参考用
Bis(eta-cyclopentadienyl) iron → Bis(eta-cyclopentadienyl) iron
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Bis(eta-cyclopentadienyl) iron | HCID 7611 | — |
| 反応物 | Stannous Chloride | HCID 24479 | — |
| 反応物 | HCID 178520619 | HCID 178520619 | — |
| 反応物 | HCID 178520620 | HCID 178520620 | — |
| 触媒 | Adams' catalyst | HCID 345198 | — |
| 触媒 | Aluminum(III) Chloride | HCID 6451240 | — |
| 溶媒 | Acetic Acid | HCID 176 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | Bis(eta-cyclopentadienyl) iron | HCID 7611 | — |
| 生成物 | 4-Chlorobutyryl chloride | HCID 78370 | — |
| 生成物 | HCID 178520619 | HCID 178520619 | — |
反応手順
In an inert atmosphere, 170 mg of PtO2.xH2O (containing 80% of Pt) and 5 mg of anhydrous SnCl2 are introduced into the glass beaker. 120 cm3 of glacial acetic acid and 29.1 g (0.10 mol) of 4-chlorobutyroylferrocene whose main impurities are 1.4% by weight of ferrocene and 0.88% by weight of 1,1'-di(4-chlorobutyroyl)ferrocene are then poured in. This 4-chlorobutyroylferrocene was obtained in the customary manner by a reaction of the Friedel-Crafts type between ferrocene and 4-chlorobutyryl chloride in CH2Cl2 in the presence of AlCl3 as catalyst, followed by recrystallisation of the crude product obtained from hexane.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05214175 |
| 出典データセット | uspto-grants-1993_05 |
| ORD ID | ord-7535c6cada5e4d8aa4c298bdb54a4fc2 |
| 出典メモ | uspto-grants-1993_05 |