Carbon Dioxide → HCID 87176092、化合物

HRID 251788

反応式

HRID 251788 の反応式
[CH:1]([N:4]([CH:8]([CH3:10])[CH3:9])[CH2:5][CH2:6][OH:7])([CH3:3])[CH3:2].[C:11](=[O:14])(O)[O-].[Na+].O.[N:17]1[C:24](Cl)=[N:23][C:21](Cl)=[N:20][C:18]=1[Cl:19].C(=O)=O>>[Cl:19][C:18]1[N:17]=[C:24]([O:7][CH2:6][CH2:5][N:4]([CH:8]([CH3:10])[CH3:9])[CH:1]([CH3:3])[CH3:2])[N:23]=[C:21]([O:14][CH2:11][CH2:5][N:4]([CH:8]([CH3:10])[CH3:9])[CH:1]([CH3:3])[CH3:2])[N:20]=1

参加物

6

反応物 5

HCID 280Carbon DioxideHCID 962WaterHCID 73132-DiisopropylaminoethanolHCID 7954Cyanuric chlorideHCID 516892Sodium Bicarbonate

生成物 1

HCID 87176092HCID 87176092、化合物

反応条件

温度
30 °C

実験手順

To 27.6 g (190 mmole) of 2-(diisopropylamino)ethanol, 6.83 g (81 mmole) of sodium bicarbonate, and 1.3 mL (70 mmole) of deionized water at room temperature was added 5.0 g (27 mmole) of cyanuric chloride. The temperature of the solution was raised to 30° C. and stirred for 1 hour at which time the evolution of carbon dioxide ceased. The temperature of the solution was raised to 45° C. and stirring was continued overnight. After cooling, the mixture was filtered, and the solids rinsed with methylene chloride. The combined filtrates were concentrated in vacuo to 6 g of 2-chloro-4,6-di-(2-(diisopropylamino)ethoxy)-1,3,5-triazine as a liquid.

後処理

  1. temperatureThe temperature of the solution was raised to 45° C.
  2. temperatureAfter cooling
  3. filtrationthe mixture was filtered
  4. washthe solids rinsed with methylene chloride
  5. concentrationThe combined filtrates were concentrated in vacuo to 6 g of 2-chloro-4,6-di-(2-(diisopropylamino)ethoxy)-1,3,5-triazine as a liquid

出典と根拠

ORDレコード
ord-58e74cf30b094bda837fad850afab2bf
出典データセット
uspto-grants-2011_01
特許番号
US07867774B2

関連ノート

読み込み中…