関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Hydrochloric Acid | HCID 313 | — |
| 反応物 | 1,4-Dioxane | HCID 31275 | — |
| 反応物 | Sodium Perchlorate | HCID 522606 | — |
| 反応物 | 2-Acetyl-9,10-dimethylanthracene | HCID 12438772 | — |
| 生成物 | 9,10-Dimethylanthracene-2-carboxylic acid | HCID 23109523 | — |
反応手順
9,10-Dimethyl-2-acetylanthracene (1.2 g) was dissolved in dioxane (24 mL). An aqueous solution of sodium perchlorate (10 mL; effective chlorine concentration: 10 wt %) was then added, followed by reaction under stirring at 85° C. for 8 hours. The reaction mixture was chilled, and then rendered acidic with dilute hydrochloric acid. The resulting precipitate was collected by filtration, washed with a small amount of water, and then dried in vacuo to afford the target compound (1.16 g).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US07873398B2 |
|---|
| 出典データセット | uspto-grants-2011_01 |
|---|
| ORD ID | ord-5f7a876a073c4b00ae30c9a328e015bf |
|---|
| 出典メモ | uspto-grants-2011_01 |
|---|
