CID 53628100 → HCID 178436245、化合物

反応式

[CH2:1]([C:3]1[CH:8]=[CH:7][CH:6]=[C:5](OC)[C:4]=1/[CH:11]=[N:12]/[CH:13]([CH:17]([CH3:19])[CH3:18])[CH:14]([CH3:16])[CH3:15])[CH3:2].[CH:20]([Li])([CH2:22][CH3:23])[CH3:21]>>[CH:20]([C:5]1[CH:6]=[CH:7][CH:8]=[C:3]([CH2:1][CH3:2])[C:4]=1/[CH:11]=[N:12]/[CH:13]([CH:14]([CH3:15])[CH3:16])[CH:17]([CH3:19])[CH3:18])([CH2:22][CH3:23])[CH3:21]

参加物

反応物 2

HCID 178418400CID 53628100

HCID 178436445HCID 178436445、化合物

生成物 1

HCID 178436245HCID 178436245、化合物

実験手順

rac-(E)-[1-(2-sec-Butyl-6-ethyl-phenyl)-methylidene]-(1-isopropyl-2-methyl-propyl)-amine was prepared from (E)-[1-(2-ethyl-6-methoxy-phenyl)-methylidene]-(1-isopropyl-2-methyl-propyl)-amine (Example 3 a) and sec.-butyl lithium in analogy to procedure Example 5 a): colourless liquid: MS (ISP): 288.1 ((M+H)+.).

出典と根拠

ORDレコード: ord-fddaa8f2c0264811b166dfd67fd70cd9
出典データセット: uspto-grants-2011_01
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07875645B2

反応ノート

読み込み中…