Dichloromethane → N-methoxymethyl-N-methylpyrrolidinium hexafluorophosphate

HRID 254896ノート

反応式

HRID 254896 の反応式
[Cl-].[CH3:2][O:3][CH2:4][N+:5]1([CH3:10])[CH2:9][CH2:8][CH2:7][CH2:6]1.[F:11][P-:12]([F:17])([F:16])([F:15])([F:14])[F:13].[Na+].ClCCl>O>[F:11][P-:12]([F:17])([F:16])([F:15])([F:14])[F:13].[CH3:2][O:3][CH2:4][N+:5]1([CH3:10])[CH2:9][CH2:8][CH2:7][CH2:6]1

参加物

5

反応物 3

HCID 6344DichloromethaneHCID 5147921Sodium hexafluorophosphateHCID 23116042N-methoxymethyl-N-methylpyrrolidinium chloride

生成物 1

HCID 86610880N-methoxymethyl-N-methylpyrrolidinium hexafluorophosphate収率 70.1%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

In 120 g of water was dissolved 20.0 g of N-methoxymethyl-N-methylpyrrolidinium chloride and thereto was added 20.3 g of sodium hexafluorophosphate to obtain a white solid. The mixture was stirred for 30 minutes, and dichloromethane was added to the mixture for extraction. The extract was washed with 20 g of water 15 times, thereafter dried, giving 23.3 g of the desired product in the form of a white solid.

後処理

  1. customto obtain a white solid
  2. washThe extract was washed with 20 g of water 15 times
  3. customdried

出典と根拠

ORDレコード
ord-853e21966797478290b8e7cb0f93fbc2
出典データセット
uspto-grants-2011_01
特許番号
US07875732B2

反応ノート

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