Paraoxon → 4-Nitrophenol

HRID 254912

反応式

HRID 254912 の反応式
[CH3:1][CH2:2][O:3][P:4]([O:9][C:10]1[CH:11]=[CH:12][C:13]([N+:16]([O-:18])=[O:17])=[CH:14][CH:15]=1)([O:6][CH2:7][CH3:8])=[O:5]>CO>[P:4]([O:9][CH3:10])([O:6][CH2:7][CH3:8])([O:3][CH2:2][CH3:1])=[O:5].[CH:12]1[C:13]([N+:16]([O-:18])=[O:17])=[CH:14][CH:15]=[C:10]([OH:9])[CH:11]=1

参加物

4

反応物 1

HCID 9395Paraoxon

生成物 2

HCID 9804-NitrophenolHCID 120420Diethyl methyl phosphate

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

Paraoxon, when placed in an appropriately buffered methanol solution containing La3+ ions held in a sspH region between 7 and 11, underwent rapid methanolysis at ambient temperature to produce diethyl methyl phosphate and p-nitrophenol. A detailed reaction scheme is given in Scheme 1.

後処理

  1. additioncontaining La3+ ions
  2. customheld in a sspH region between 7 and 11, underwent rapid methanolysis at ambient temperature

出典と根拠

ORDレコード
ord-b86319d51abd4abb96b475cbeb2667c0
出典データセット
uspto-grants-2011_01
特許番号
US07875739B2

関連ノート

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