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Benzene, 1-chloro-3-isocyanato- → Phenyl-(3-chlorophenylaminocarbonyloxy)-malonic acid diamide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Benzene, 1-chloro-3-isocyanato- | HCID 17968 | — |
| 反応物 | 2-Hydroxy-2-phenylmalonamide | HCID 13180061 | — |
| 触媒 | Zinc Caprylate | HCID 11180 | — |
| 溶媒 | Ethyl Acetate | HCID 8857 | — |
| 生成物 | Phenyl-(3-chlorophenylaminocarbonyloxy)-malonic acid diamide | HCID 13361940 | 55.6% |
反応手順
0.5 g of zinc octoate and 4.45 g of 3-chlorophenyl isocyanate were added to 8.2 g of phenylhydroxymalonic acid diamide in 30 ml of ethyl acetate and the mixture was kept at 50° C. for 30 minutes. After cooling, the precipitate was filtered off with suction and recrystallised from acetone. 5.6 g of phenyl-(3-chlorophenylaminocarbonyloxy)-malonic acid diamide of melting point 196°-198° C. were obtained.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04698333 |
| 出典データセット | uspto-grants-1987_10 |
| ORD ID | ord-f4aee39cd75a4c03922b1961aa114d69 |
| 出典メモ | uspto-grants-1987_10 |