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2-Amino-5-methylbenzoic acid → HCID 13959036、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Amino-5-methylbenzoic acid | HCID 76255 | — |
| 反応物 | 2-Amino-3-methylbenzoic acid | HCID 78101 | — |
| 反応物 | Methyl 2-Amino-5-methylbenzoate | HCID 1201104 | — |
| 反応物 | 2-(2-Amino-5-methyl-phenyl)-propan-2-ol | HCID 13959001 | — |
| 反応物 | 2-(2-Amino-5-methylphenyl)propene | HCID 13959003 | — |
| 反応物 | 4,6-Dimethylcinnoline | HCID 13959005 | — |
| 反応物 | 6-Methyl-4-(trichloromethyl)cinnoline | HCID 13959007 | — |
| 生成物 | HCID 13959036 | HCID 13959036 | — |
反応手順
51 was prepared, as a tan solid, m.p.: 179°-180° C., from 2-amino-5-methylbenzoic acid, by the respective procedures described in Example 49 for preparing 49 from 2-amino-3-methylbenzoic acid: via methyl 2-amino-5-methylbenzoate (a solid, m.p.: 62°-63° C.), (2-amino-5-methylphenyl)dimethylcarbinol (an oil, b.p.: 100° C./0.1 Torr.), 2-(2-amino-5-methylphenyl)propene (a liquid, b.p.: 87°-90° C./0.5 Torr.), 4,6-dimethylcinnoline (a solid, m.p.: 75°-76° C.), and 6-methyl-4-(trichloromethyl)cinnoline (green crystals, m.p.: 132°-133° C., with decomposition).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04699651 |
| 出典データセット | uspto-grants-1987_10 |
| ORD ID | ord-064095af81d340538ef50470603e61ca |
| 出典メモ | uspto-grants-1987_10 |