1-Chloroanthraquinone → 1-Butylphenylamino anthraquinone

HRID 256278

反応式

HRID 256278 の反応式
Cl[C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[CH:5]=[CH:4][CH:3]=1.C([NH:22][C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1)CCC.C([O-])(=O)C.[Na+].[N+]([C:37]1[CH:42]=CC=[CH:39][CH:38]=1)([O-])=O>C([O-])(=O)C.[Cu+2].C([O-])(=O)C>[CH2:42]([C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[CH:5]=[CH:4][C:3]=1[NH:22][C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1)[CH2:37][CH2:38][CH3:39]

参加物

6

反応物 4

HCID 67091-ChloroanthraquinoneHCID 7416NitrobenzeneHCID 14310N-Butylaniline2 回HCID 517045Sodium Acetate

生成物 1

HCID 704309131-Butylphenylamino anthraquinone

試薬・触媒・溶媒 1

HCID 8895Cupric acetate触媒

実験手順

The pleochroic dye 1-butylphenylamino anthraquinone was prepared by dissolving 1-chloroanthraquinone in a 10-fold excess of 4-n butylaniline. Copper acetate and sodium acetate were added as in Example 70. Since the n-butylaniline is a solvent in this case no nitrobenzene was added. The dye, when tested as in Example 70, had an absorption maxima at 515 nm and an order parameter of 0.65.

後処理

  1. additionwas added

出典と根拠

ORDレコード
ord-ca152b54d7c748e2af8679ae4be944b8
出典データセット
uspto-grants-1987_10
特許番号
US04702561

関連ノート

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