Stannane, chlorotris(2-methyl-2-phenylpropyl)- → Tris(beta,beta-dimethylphenethyl)tin caprylate

HRID 256383ノート

反応式

HRID 256383 の反応式
[C:1]([O-:10])(=[O:9])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[Na+].[CH3:12][C:13]([CH3:43])([C:37]1[CH:42]=[CH:41][CH:40]=[CH:39][CH:38]=1)[CH2:14][Sn:15](Cl)([CH2:26][C:27]([CH3:35])([CH3:34])[C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1)[CH2:16][C:17]([CH3:25])([CH3:24])[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1>C(O)(C)C>[C:1]([O-:10])(=[O:9])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[CH3:24][C:17]([CH3:25])([C:18]1[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=1)[CH2:16][Sn+:15]([CH2:26][C:27]([CH3:34])([CH3:35])[C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1)[CH2:14][C:13]([CH3:12])([CH3:43])[C:37]1[CH:42]=[CH:41][CH:40]=[CH:39][CH:38]=1

参加物

4

反応物 2

HCID 70898Stannane, chlorotris(2-methyl-2-phenylpropyl)-HCID 23664772Sodium octanoate

生成物 1

HCID 20163799Tris(beta,beta-dimethylphenethyl)tin caprylate収率 94.8%

試薬・触媒・溶媒 1

HCID 3776Isopropanol溶媒

反応条件

温度
50 °C

実験手順

Sodium caprylate 6.6 g was added to 200 ml of isopropanol, and with stirring, the mixture was heated to 50° C. To the resulting solution was added 22.2 g of tris(β,β-dimethylphenethyl)tin chloride over 30 minutes. The mixture was further stirred for 30 minutes. The insoluble material precipitated was separated by filtration, and the filtrate was concentrated to give 25.1% (yield 94.8%) of tris(β,β-dimethylphenethyl)tin caprylate as a slightly pale yellow viscous syrup.

後処理

  1. stirringThe mixture was further stirred for 30 minutes
  2. customThe insoluble material precipitated
  3. customwas separated by filtration
  4. concentrationthe filtrate was concentrated

出典と根拠

ORDレコード
ord-f8127e71572a42c085d969477bdc91a0
出典データセット
uspto-grants-1987_10
特許番号
US04703059

反応ノート

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