2-Bromo-1,1,1-trifluoroethane → Bis(trifluoroethyl)dithio
反応式
[F:1][C:2]([F:6])([F:5])[CH2:3]Br.O.O.O.O.O.O.O.O.O.[S-2:16].[Na+].[Na+].[S]>[Br-].C([P+](CCCC)(CCCC)CCCC)CCCCCCCCCCCCCCC.O>[F:1][C:2]([F:6])([F:5])[CH2:3][S:16][S:16][CH2:3][C:2]([F:6])([F:5])[F:1]参加物
6
反応条件
- 温度
- 70 °C
実験手順
A mixture of 2,2,2-trifluoroethyl bromide (9.8 g), sodium sulphide nonahydrate (14.4 g), sulphur (1.9 g), hexadecyl tributyl phosphonium bromide (1.0 g) and water (18.0 g) was charged to a Carius tube under a nitrogen atmosphere and the tube sealed. The tube was heated to 70° C. for 8 hours, cooled and the contents subjected to steam distillation to give bis-(2,2,2-trifluoroethyl) disulphide as an oil in a yield of 67° C. The product was identified by GC-mass spectroscopy.
後処理
- additionwas charged to a Carius tube under a nitrogen atmosphere
- customthe tube sealed
- temperaturecooled
- distillationthe contents subjected to steam distillation
出典と根拠
- ORDレコード
- ord-70a8131d2c2242bda19952751b86f54d
- 出典データセット
- uspto-grants-1993_11
- 特許番号
- US05258547
反応ノート
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