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Cyclohexanone → Prop-2-enenitrile--ethenylbenzene (1/1)
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Cyclohexanone | HCID 7967 | — |
| 反応物 | Isoquinoline | HCID 8405 | — |
| 触媒 | Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI) | HCID 24350 | — |
| 溶媒 | N-methyl-2-pyrrolidone | HCID 13387 | — |
| 生成物 | Prop-2-enenitrile--ethenylbenzene (1/1) | HCID 62696 | 10% |
反応手順
A solution of 2.0 g. CuI, 1.4 g. isoquinoline (1:1 ratio), 50.0 g. N-methylpyrrolidone solvent, 46.6 g. cyclohexanone and 0.20 g. Lustran SAN 31-1,000 (10% on CuI) was prepared. The resulting coating solution was coated on 7 mil raw PET with number 10 Meyer rod and dried three minutes at 240° F. The coating had very good uniformity and clarity and was gold and blue iridescent and lustrous. The resistivity measured 13-20×107 Ω/sq. The solution after time showed some precipitation, which crystals were redissolved upon reheating.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05259992 |
| 出典データセット | uspto-grants-1993_11 |
| ORD ID | ord-3110b0bfc3814e4280160de68cfb5d7b |
| 出典メモ | uspto-grants-1993_11 |