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Benzyl acetone → (E)-1-(3-ethyl-4-pyridyl)-2-methyl-4-phenyl-1-butene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Benzyl acetone | HCID 17355 | — |
| 反応物 | 3-Ethyl-4-methylpyridine | HCID 68254 | — |
| 生成物 | (E)-1-(3-ethyl-4-pyridyl)-2-methyl-4-phenyl-1-butene | HCID 14883803 | 69.5% |
反応手順
The procedure of Example 41 was repeated with the exception that 3.5 g of benzyl acetone in place of cinnamic aldehyde and 2.26 g of 3-ethyl-4-methylpyridine were used in Example 41, to obtain 3.26 g (yield: 59.8%) of (E)-1-(3-ethyl-4-pyridyl)-2-methyl-4-phenyl -1-butene (hereinafter referred to as compound 55) and o.95 g (yield: 17.4%) of (Z)-1-(3-ethyl-4-pyridyl)-2-methyl-4-phenyl-1-butene (hereinafter referred to as compound 56). The analytical results are shown below.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05262420 |
| 出典データセット | uspto-grants-1993_11 |
| ORD ID | ord-8b990d7f82d54f9b834fc6ef6159ea3e |
| 出典メモ | uspto-grants-1993_11 |