1-Bromo-3-tert-butylbenzene → (3-tert-Butyl-phenylethynyl)-trimethyl-silane

HRID 257987

反応式

HRID 257987 の反応式
[CH3:1][Si:2]([C:5]#[C:6][C:7]1[CH:12]=[CH:11][C:10](C(C)(C)C)=[CH:9][CH:8]=1)([CH3:4])[CH3:3].[C:17](C1C=C(Br)C=CC=1)([CH3:20])([CH3:19])[CH3:18]>>[CH3:4][Si:2]([C:5]#[C:6][C:7]1[CH:8]=[CH:9][CH:10]=[C:11]([C:17]([CH3:20])([CH3:19])[CH3:18])[CH:12]=1)([CH3:1])[CH3:3]

参加物

3

反応物 2

HCID 3437981-Bromo-3-tert-butylbenzene2 回HCID 14989664((4-(tert-Butyl)phenyl)ethynyl)trimethylsilane

生成物 1

HCID 14989665(3-tert-Butyl-phenylethynyl)-trimethyl-silane

実験手順

Using the same general procedure as described for Compound 21, but using 3-tert-butyl-bromobenzene, (Compound 24) the title compound was synthesized as a colorless oil. PMR (CDCl3): & 0.36 (9H, s), 1.40 (9H, s), 7.32 (1H, m), 7.37-7.47 (2H, m), 7.61 (1H, m).

出典と根拠

ORDレコード
ord-32841561546241059a0ed804a4358357
出典データセット
uspto-grants-1993_11
特許番号
US05264456

関連ノート

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