関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Hydrochloric Acid | HCID 313 | — |
| 反応物 | Diethyl Carbonate | HCID 7766 | — |
| 反応物 | 1-Bromodecane | HCID 8173 | — |
| 反応物 | Magnesium | HCID 5462224 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | Tri-n-decylcarbinol | HCID 19690419 | — |
反応手順
Three moles of 1-bromodecane was slowly added to 3 moles of magnesium turnings in 0.6 liters of anhydrous ethyl ether (nitrogen atmosphere). One mole of diethyl carbonate in 0.151 anhydrous ethyl ether was slowly added to the mixture. After stirring for one hour at 30° C., the mixture was slowly poured into 1.8 liters of a cold 10% HCl solution. The organic layer was dried with magnesium sulfate and the ethyl ether evaporated off to give tri-n-decylcarbinol.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05728907 |
|---|
| 出典データセット | uspto-grants-1998_03 |
|---|
| ORD ID | ord-5831ca84c85c45188e821732a2150987 |
|---|
| 出典メモ | uspto-grants-1998_03 |
|---|
